You want indexing to be enabled, actually, you just want the drive in privacy (which disables indexing a different way).
If you can't get it to add to the Privacy tab, it's likely that the .Spotlight_V100 folder, at the top of the drive, is corrupt.
Try removing this folder. Then, restart your Mac. Once restarted, add it to the Spotlight Privacy tab, and I think it'll work properly.
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--Dave Nanian
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